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searching for Aldol condensation 32 found (145 total)

Dibenzyl ketone (182 words) [view diff] exact match in snippet view article find links to article

nucleophilic. For this reason, dibenzyl ketone is frequently used in an aldol condensation reaction with benzil (a dicarbonyl) and base to create tetraphenylcyclopentadienone

Acetyl cyanide (406 words) [view diff] exact match in snippet view article find links to article

can occur with acetyl cyanide as a reactant; aldol condensation and enolate substitution. Aldol condensation can occur when acetyl cyanide reacts with (Z)-but-2-enal

Parikh–Doering oxidation (495 words) [view diff] exact match in snippet view article find links to article

Ohira-Bestmann homologation, which is critical in the following 1,4 addition/aldol condensation/dehydration cascade that forms cortistatins' seven-membered ring.

Bemegride (331 words) [view diff] exact match in snippet view article find links to article

cyanoacetamide. The product can be rationalized by assuming first aldol condensation of ketone and active methylene compound followed by dehydration to

Cascade reaction (2,826 words) [view diff] exact match in snippet view article find links to article

obtained selectively. The cascade was completed by an intramolecular aldol condensation that afforded product 11 in 76% overall yield. Further elaboration

Triflate (597 words) [view diff] exact match in snippet view article find links to article

Sc(OTf)3-mediated aldol condensation

AL-1095 (231 words) [view diff] exact match in snippet view article find links to article

amphetamine, developed by Bristol in the 1970s. The first-step is a mixed-aldol condensation between 3-quinuclidinone [3731-38-2] (1) and benzaldehyde (2) gives

Scandium(III) trifluoromethanesulfonate (181 words) [view diff] exact match in snippet view article

Sc(OTf)3-mediated aldol condensation

Propionyl chloride (194 words) [view diff] case mismatch in snippet view article find links to article

ISBN 978-0-12-800807-2. Gage, James R.; Evans, David A. (1990). "Diastereoselective Aldol Condensation Using a Chiral Oxazolidinone Auxiliary: (2S,3S)-3-Hydroxy-3-phenyl-2-methylpropanoic

2,5-Diketopiperazine (2,289 words) [view diff] exact match in snippet view article find links to article

nucleophiles SR, OR, NR2, alkyl and aryl to give 7 . A one- or two-fold aldol condensation of N-acetylated 2,5-DKP 8 gives access to 3-dehydro-2,5-diketopiperazines

Methanediol (430 words) [view diff] exact match in snippet view article find links to article

October 2011. Bell, R. P.; McTigue, P. T. (1960). "603. Kinetics of the aldol condensation of acetaldehyde". Journal of the Chemical Society (Resumed): 2983

Multiple Michael/aldol reaction (338 words) [view diff] exact match in snippet view article find links to article

annulation, a classic reaction involving a Michael addition followed by an aldol condensation Posner, Gary H.; Webb, Kevin S.; Asirvatham, Edward; Jew, Sang Sup;

Piperolactam A (341 words) [view diff] case mismatch in snippet view article find links to article

Synthesis of Aristolactams via a One-Pot Suzuki−Miyaura Coupling/Aldol Condensation Cascade Reaction". Organic Letters. 10 (16): 3543–3546. doi:10.1021/ol801291k

Farinamycin (335 words) [view diff] exact match in snippet view article find links to article

L-Aspartate-4-semialdehyde and Dihydroxyacetone phosphate via an enzyme catalyzed aldol condensation followed by ring formation. Enaminomycin C is formed from anthranilate

David A. Evans (826 words) [view diff] case mismatch in snippet view article find links to article

Harvard University. Retrieved March 14, 2017. "Diastereoselective Aldol Condensation Using a Chiral Oxazolidinone Auxiliary: (2S,3S)-3-Hydroxy-3-Phenyl-2-Methylpropanoic

Titanium compounds (1,234 words) [view diff] exact match in snippet view article find links to article

in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation. In the van Arkel–de Boer process, titanium tetraiodide (TiI4) is

3-dehydroquinate synthase (842 words) [view diff] exact match in snippet view article find links to article

β-elimination, carbonyl reduction, ring opening, and intramolecular aldol condensation. Dehydroquinate synthase requires NAD+ and a cobalt cofactor to catalyze

Stetter reaction (2,357 words) [view diff] exact match in snippet view article find links to article

utilized if a thiazolium salt is used as a catalyst, as they undergo aldol condensation side reaction when a cyanide catalyst is used. In addition, α,β-unsaturated

Fischer carbene (1,435 words) [view diff] exact match in snippet view article find links to article

fluorosulfonate ("magic methyl" reagent) or methyl bromoacetate is needed. Aldol condensation of Fischer carbenes could be achieved by using much weaker bases compared

Red oil (485 words) [view diff] exact match in snippet view article find links to article

caustic towers. The "red oil" is an organic polymer that forms from the aldol condensation of acetaldehyde in sodium hydroxide solution. Initially, the acetaldehyde

Hydrogen auto-transfer (1,574 words) [view diff] exact match in snippet view article find links to article

alcohols to β-alkylated dimers via alcohol dehydrogenation followed by aldol condensation and reduction of the resulting enones. Application of the Guerbet

Hiizu Iwamura (1,259 words) [view diff] exact match in snippet view article find links to article

a number of preparative organic reactions that proceed by way of aldol condensation and Michael addition in sub- or supercritical water in the absence

Α-Isomethyl ionone (402 words) [view diff] exact match in snippet view article find links to article

or Vetiver. The synthesis of α-isomethyl ionone involves a cross-aldol condensation of citral with methyl ethyl ketone A high temperature and strong alkali

Indigo dye (3,927 words) [view diff] exact match in snippet view article find links to article

Baeyer–Drewsen indigo synthesis dates back to 1882. It involves an aldol condensation of o-nitrobenzaldehyde with acetone, followed by cyclization and oxidative

Hydroformylation (3,102 words) [view diff] exact match in snippet view article find links to article

of hydrogen. The initially produced aldehydes can react further by aldol condensation to either target product precursors like 2-ethylhexenal or higher

Methylotroph (3,412 words) [view diff] exact match in snippet view article find links to article

ribulose-5-phosphate, 3 molecules of formaldehyde form a C-C bond through an aldol condensation, producing 3 C 6 {\displaystyle {\ce {C6}}} molecules of 3-hexulose

Acetaldehyde (5,159 words) [view diff] exact match in snippet view article find links to article

These imines can be used to direct subsequent reactions like an aldol condensation. It is also a building block in the synthesis of heterocyclic compounds

Titanium (8,448 words) [view diff] exact match in snippet view article find links to article

in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation. In the van Arkel–de Boer process, titanium tetraiodide (TiI4) is

MACBETH project (1,617 words) [view diff] exact match in snippet view article find links to article

reaction conditions on the accumulation and activity in the gas-phase aldol condensation of n-pentanal on porous silica". Reaction Chemistry & Engineering

Rhododendrol (2,164 words) [view diff] exact match in snippet view article find links to article

steps from benzaldehyde. The key reactions in this method include aldol condensation and trichloroacetimidate glycosylation. The compound can also be prepared

Xanthatin (1,885 words) [view diff] exact match in snippet view article find links to article

desired α-exo-methylene-γ-butyrolactone group was formed. A Makaiyama aldol condensation with trimethyl(prop-1-en-2-yloxy)silane is added for the complete

John P. Richard (2,240 words) [view diff] exact match in snippet view article find links to article

work has led to the identification of novel nonenzymatic Claisen and aldol condensation reactions of pyridoxal cofactor analogs, and results from collaborative