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Longer titles found: Silicon alkoxide (view), Transition metal alkoxide complex (view)

searching for Alkoxide 115 found (239 total)

alternate case: alkoxide

Luche reduction (334 words) [view diff] exact match in snippet view article find links to article

hardness of the borohydride is increased by replacing hydride groups with alkoxide groups, a reaction catalyzed by the cerium salt by increasing the electrophilicity

Tantalum(V) ethoxide (1,686 words) [view diff] exact match in snippet view article

readily. It is used to prepare films of tantalum(V) oxide. Tantalum(V) alkoxides typically exist as dimers with octahedral six-coordinate tantalum metal

Niobium(V) ethoxide (459 words) [view diff] exact match in snippet view article

Metal alkoxides rarely adopt monomeric structures, and niobium(V) ethoxide is no exception. Early studies established that niobium alkoxides aggregate

Saponification (1,246 words) [view diff] exact match in snippet view article find links to article

the alkoxide generates a carboxylic acid: The alkoxide ion is a strong base so the proton is transferred from the carboxylic acid to the alkoxide ion

McFadyen–Stevens reaction (280 words) [view diff] exact match in snippet view article find links to article

sulfonamide followed by a 1,2-hydride migration to give the alkoxide (3). The collapse of the alkoxide results in the fragmentation producing the desired aldehyde

Deprotonation (643 words) [view diff] exact match in snippet view article find links to article

For example, deprotonation of an alcohol forms the negatively charged alkoxide, which is a much stronger nucleophile. To determine whether or not a given

Red rot (363 words) [view diff] exact match in snippet view article find links to article

progress of red rot can be stopped or slowed with a treatment of aluminium alkoxide solution, which increases the pH value and becomes (in the presence of

Trimethyl borate (372 words) [view diff] exact match in snippet view article find links to article

borate is the organoboron compound with the formula B(OCH3)3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. It is an intermediate

Elimination reaction (1,843 words) [view diff] exact match in snippet view article find links to article

For example, when a 3° haloalkane reacts with an alkoxide, due to strong basic character of the alkoxide and unreactivity of 3° group towards SN2, only

Wolff–Kishner reduction (4,211 words) [view diff] exact match in snippet view article find links to article

determining step of the reaction is de-protonation of the hydrazone by an alkoxide base to form a diimide anion by a concerted, solvent mediated protonation/de-protonation

Acetylenediol (674 words) [view diff] no match in snippet view article find links to article

Acetylenediol, or ethynediol, is a chemical substance with formula HO−C≡C−OH (an ynol). It is the diol of acetylene. Acetylenediol is unstable in the condensed

Diethyl malonate (765 words) [view diff] exact match in snippet view article find links to article

malonate and the alcohol, while other alkoxide salts will cause scrambling by transesterification. Only the "same" alkoxide anion as the one that one used to

Triethylgallium (340 words) [view diff] exact match in snippet view article find links to article

AlClEt2 Triethylgallium readily converts to the air-stable, colorless alkoxide by two routes, oxidation and alcoholysis: GaEt3 + 0.5 O2 → GaEt2(OEt) GaEt3

Baylis–Hillman reaction (2,788 words) [view diff] exact match in snippet view article find links to article

after the first aldol addition, a second aldol adds to form a hemiacetal alkoxide. Then the rate-determining proton transfer releases the adduct A via a

Aston–Greenburg rearrangement (159 words) [view diff] exact match in snippet view article find links to article

corresponding α-haloketones through a 1,2-rearrangement, with the use of an alkoxide. Aston, J. G.; Greenburg, R. B. (1942). "alpha-Bromo Secondary Alkyl Ketones

1,2-Wittig rearrangement (361 words) [view diff] exact match in snippet view article find links to article

only shows the rearranged product 5 but not 4 after trapping the lithium alkoxide with trimethylsilyl chloride. This result rules out a radical-ketyl intermediate

Appel reaction (685 words) [view diff] exact match in snippet view article find links to article

alcohol, forming chloroform, yields an alkoxide 5. The nucleophilic displacement of the chloride by the alkoxide yields intermediate 7. With primary and

Krische allylation (2,045 words) [view diff] exact match in snippet view article find links to article

π-allyliridium precatalyst to generate the iridium alkoxide I. β-Hydride elimination of alkoxide I generates the aldehyde, which dissociates to form

Chan–Lam coupling (621 words) [view diff] exact match in snippet view article find links to article

proceeds via the formation of copper-aryl complexes. A copper(III)-aryl-alkoxide or copper(III)-aryl-amide intermediate undergoes Reductive elimination

Glycerol dehydrogenase (1,209 words) [view diff] exact match in snippet view article find links to article

C2 hydroxyl group, forming an alkoxide. The zinc atom further serves to stabilize the negative charge on the alkoxide intermediate before the excess

Ortho ester (501 words) [view diff] exact match in snippet view article find links to article

were first produced by reaction of 1,1,1-trichloroalkanes with sodium alkoxide: RCCl3 + 3 NaOR′ → RC(OR′)3 + 3 NaCl Ortho esters are readily hydrolyzed

Trifluoromethyltrimethylsilane (506 words) [view diff] exact match in snippet view article find links to article

intermediate. The [CF3]− attacks the carbonyl to generate an alkoxide anion. The alkoxide is silylated by the reagent to give the overall addition product

Payne rearrangement (1,773 words) [view diff] exact match in snippet view article find links to article

epoxy alcohol isomer. Intramolecular electrophilic trapping of the new alkoxide generated upon rearrangement may also be used to drive the reaction to

Vyacheslav Tishchenko (544 words) [view diff] exact match in snippet view article find links to article

115. ISBN 9783642282195. Ogata, Y; Kawasaki, A (1969). "Alkoxide transfer from aluminium alkoxide to aldehyde in the Tishchenko reaction". Tetrahedron.

William B. Tolman (1,871 words) [view diff] exact match in snippet view article find links to article

biodegradable polymers. An example of this work is the use of Zn(II) or Fe(III) alkoxide catalysts, which can polymerize lactide (LA) into polylactic acid (PLA)

Sodium borohydride (2,615 words) [view diff] exact match in snippet view article find links to article

to alcohols. These reductions proceed in two stages, formation of the alkoxide followed by hydrolysis: NaBH4 + 4 R2C=O → NaO−CHR2 + B(O−CHR2)3 NaO−CHR2

Stobbe condensation (224 words) [view diff] exact match in snippet view article find links to article

or related derivatives. The reaction consumes one equivalent of metal alkoxide. Commonly, diethylsuccinate is a component of the reaction. The usual product

Peterson olefination (727 words) [view diff] exact match in snippet view article find links to article

to date.[when?] Potassium alkoxides eliminate quickly, while sodium alkoxides generally require heating. Magnesium alkoxides only eliminate in extreme

Nonafluoro-tert-butyl alcohol (205 words) [view diff] exact match in snippet view article find links to article

halogen exchange with antimony pentafluoride. The aluminate derived from its alkoxide anion, tetrakis[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-oxy]aluminate(1–)

L-selectride (380 words) [view diff] exact match in snippet view article find links to article

effected in two steps: delivery of the hydride equivalent to give the lithium alkoxide followed by hydrolytic workup: R2CO + Li[(CH3CH2CH(CH3))3BH] → R2CHOLi

Pinacol rearrangement (969 words) [view diff] exact match in snippet view article find links to article

believed acetone to be an alcohol which he hoped to prove by forming a metal alkoxide salt. The reaction product he obtained instead he called paraceton which

Electrophilic amination (2,074 words) [view diff] exact match in snippet view article find links to article

example), the resulting alkoxide reacts further to afford unexpected products. Straightforward β-elimination of the alkoxide leads to the formation of

Prins reaction (1,068 words) [view diff] exact match in snippet view article find links to article

diastereoselectivity is due to the intermediate formation of a trichlorotitanium alkoxide making possible an easy delivery of chlorine to the carbocation ion from

Ullmann condensation (800 words) [view diff] exact match in snippet view article find links to article

etherifications, etc. of aryl halides), the conversions involve copper(I) alkoxide, copper(I) amides, copper(I) thiolates. The copper(I) reagent can be generated

Polyester (5,185 words) [view diff] exact match in snippet view article find links to article

the alcohol (generally in fact a phenol) is dissolved in the form of an alkoxide in an aqueous sodium hydroxide solution, the acyl chloride in an organic

Alkyne metathesis (1,309 words) [view diff] exact match in snippet view article find links to article

formation of a deprotio-metallacyclobutadiene and concomitant loss of one alkoxide ligand. This reaction course remains viable for the new alkylidynes with

(4+3) cycloaddition (1,268 words) [view diff] exact match in snippet view article

solvents are more effective than their non-fluorinated analogues, and alkoxide or amine bases work better than others. [6+4] cycloaddition IUPAC Nomenclature

Cyclopropanation (1,505 words) [view diff] exact match in snippet view article find links to article

reaction between esters and Grignard reagents in presence of a titanium alkoxide. The Bingel reaction is a specialised cyclopropanation reaction used to

(4+3) cycloaddition (1,268 words) [view diff] exact match in snippet view article

solvents are more effective than their non-fluorinated analogues, and alkoxide or amine bases work better than others. [6+4] cycloaddition IUPAC Nomenclature

Metallacarboxylic acid (323 words) [view diff] exact match in snippet view article find links to article

LnMCO2−. Metallacarboxylate esters (LnMCO2R) arise by the addition of alkoxide to metal carbonyl: [LnM-CO]+ + ROH → [LnM-CO2R] + H+ Metallacarboxylic

Corey–Nicolaou macrolactonization (257 words) [view diff] exact match in snippet view article find links to article

corresponding 2-pyridinethiol ester, and after a proton transfer, the alkoxide attacks the carbonyl carbon, forming a tetrahedral transition state, before

Alkynylation (1,249 words) [view diff] exact match in snippet view article find links to article

lithium ethyl propiolate to which cyclopentanone is added forming a lithium alkoxide. Acetic acid is added to remove lithium and liberate the free alcohol.

Oxonium ion (1,095 words) [view diff] exact match in snippet view article find links to article

Characterisation of Silverpolyfluoroalkoxyaluminates AgAl(ORF)4, Calculation of the Alkoxide Ion Affinity". Chemistry – A European Journal. 7 (2): 490–502. doi:10

Hydroformylation (3,102 words) [view diff] exact match in snippet view article find links to article

initially forms a CO-π-complex with the catalyst. This is rearranged to the alkoxide complex and by subsequent oxidative addition of hydrogen the alcohol is

Neodymium(III) acetylacetonate (318 words) [view diff] exact match in snippet view article

Neodymium(III) acetylacetonate can be obtained by treating a neodymium alkoxide with acetylacetone, or by electrolysis of neodymium in acetylacetone. Pierson

Phenethyl alcohol (474 words) [view diff] exact match in snippet view article find links to article

CH2CH2O + AlCl3 → C6H5CH2CH2OAlCl2 + HCl The reaction affords the aluminium alkoxide that is subsequently hydrolyzed to the desired product. The main side product

Cyaphide (289 words) [view diff] exact match in snippet view article find links to article

η1-coordinated phosphaalkyne complex trans–[RuH(P≡CSiPH3)(dppe)2]+ with an alkoxide resulted in desilylation, followed by subsequent rearrangement to the corresponding

Lanthanum acetylacetonate (521 words) [view diff] exact match in snippet view article find links to article

reported for "La(acac)3". It can be prepared by the reaction of lanthanum alkoxide and acetylacetone. Its tetrahydrate decomposes into monohydrate at 110 °C

Metal–ligand multiple bond (1,027 words) [view diff] exact match in snippet view article find links to article

Classic pi-donor ligands are oxide (O2−), nitride (N3−), imide (RN2−), alkoxide (RO−), amide (R2N−), and fluoride. For late transition metals, strong pi-donors

Organolead chemistry (972 words) [view diff] exact match in snippet view article find links to article

oxyplumbation, organolead alkoxides are added to polar alkenes: H2C=CH-CN + (Et3PbOMe)n → MeO-CH2-HC(PbEt3)-CN → MeO-CH2-CH2-CN The alkoxide is regenerated in

Oxazoline (1,757 words) [view diff] exact match in snippet view article find links to article

"Deposition of HfO2 and ZrO2 films by liquid injection MOCVD using new monomeric alkoxide precursors". Journal of Materials Chemistry. 15 (19): 1896. doi:10.1039/B417389A

Yttrium compounds (1,244 words) [view diff] exact match in snippet view article find links to article

hydroxide or ammonia, and can also be obtained by the hydrolysis of yttrium alkoxide. Hydroxy acids and sugars present in the solution will prevent the formation

Cycloalkyne (1,558 words) [view diff] exact match in snippet view article find links to article

insertion of cyclohexyne into cyclic ketones. The reaction is initiated by the alkoxide-mediated generation of the reactive cycloalkyne species in situ, followed

Inorganic polymer (863 words) [view diff] exact match in snippet view article find links to article

of hexachlorophosphazene followed by substitution of the P−Cl groups by alkoxide. Such materials find specialized applications as elastomers. Boron–nitrogen

Azastene (265 words) [view diff] exact match in snippet view article find links to article

methyl iodide to afford the 4,4-dimethyl derivative. Formylation with alkoxide and methyl formate leads to the 2-hydroxymethyl derivative. Reaction of

Inositol oxygenase (1,818 words) [view diff] exact match in snippet view article find links to article

"Demonstration by 2H ENDOR spectroscopy that myo-inositol binds via an alkoxide bridge to the mixed-valent diiron center of myo-inositol oxygenase". Journal

Shibasaki catalyst (520 words) [view diff] exact match in snippet view article find links to article

from their ability to act as both a Brønsted base by virtue of the metal alkoxide and a Lewis acid via the lanthanide ion. Enantioselectivity has been found

Fischer–Speier esterification (1,402 words) [view diff] exact match in snippet view article find links to article

the leaving group is a carboxylate anion—a better leaving group than an alkoxide anion because their negative charge is more delocalised. However, such

Henry reaction (1,931 words) [view diff] exact match in snippet view article find links to article

is of the carbon attacking the carbonyl compound. The resulting β-nitro alkoxide is protonated by the conjugate acid of the base that originally deprotonated

Organotitanium chemistry (1,866 words) [view diff] exact match in snippet view article find links to article

useful than the simple tetraalkyl compounds are mixed ligand complexes with alkoxide and cyclopentadienyl coligands. Titanium is capable of forming complexes

Trypsin (2,776 words) [view diff] exact match in snippet view article find links to article

to aspartate, but owing to evidence provided by NMR that the resultant alkoxide form of serine would have a much stronger pull on the proton than does

Biodiesel production (1,930 words) [view diff] exact match in snippet view article find links to article

starting ester (RCOOR1) undergoes nucleophilic attack by the incoming alkoxide (R2O−) to give a tetrahedral intermediate, which either reverts to the

Mitsunobu reaction (1,570 words) [view diff] exact match in snippet view article find links to article

formation of the oxyphosphonium intermediate 8 is slow and facilitated by the alkoxide. Therefore, the overall rate of reaction is controlled by carboxylate basicity

Titanium disulfide (2,234 words) [view diff] exact match in snippet view article find links to article

synthesis of titanium disulfide thin films and powders using titanium alkoxide precursors". Journal of Non-Crystalline Solids. 354 (15–16): 1801–1807

Tetraketopiperazine (308 words) [view diff] exact match in snippet view article find links to article

A disodium salt results from reaction with sodium hydroxide or sodium alkoxide. These are likely to be tautomeric with a hydrogen moving to an oxygen

2,2-Diethoxytetrahydrofuran (387 words) [view diff] exact match in snippet view article find links to article

"Reacting trialkyl orthoformate with boron trifluoride and lactone, then with alkoxide or alkanol and base", published 1991-02-05, assigned to Alza Corp. Jorge

Thiosulfurous acid (666 words) [view diff] exact match in snippet view article find links to article

third isomer results from d,l-PhCH(OH)−CH(OH)Ph. The reaction with simple alkoxide sources with disulfur dichloride gives the unbranched ROSSOR. They are

Mass deacidification (2,111 words) [view diff] exact match in snippet view article find links to article

referred to as "the Battelle Process". The process uses magnesium titanium alkoxide. The Papersave process is available in Europe through Nitrochemie Wimmis

Organoboron chemistry (2,451 words) [view diff] exact match in snippet view article find links to article

alkenylborane gives an boron-free enol. Organoborane activation with hydroxide or alkoxide and treatment with X2 yields haloalkanes. With excess base, two of the

Streptomyces fimbriatus (326 words) [view diff] exact match in snippet view article find links to article

of diketene with 2,4-hexadienal promoted by chiral Schiff base-titanium alkoxide complexes". Tetrahedron: Asymmetry. 6 (10): 2511–2516. doi:10.1016/0957-4166(95)00328-M

Aromatic compound (2,104 words) [view diff] exact match in snippet view article find links to article

(C6H5–OH), which is acidic at the hydroxyl (OH), as charge on the oxygen (alkoxide –O−) is partially delocalized into the benzene ring. Although benzylic

Abramov reaction (1,098 words) [view diff] exact match in snippet view article find links to article

silyl group from an oxygen attached to phosphorus to the newly created alkoxide center. Conjugate addition is also possible, and gives γ-functionalized

Carbonyl oxidation with hypervalent iodine reagents (1,207 words) [view diff] exact match in snippet view article find links to article

relatively acidic ligands on iodine (such as acetate) have been replaced by alkoxide. In all cases, the α carbon forms a bond to iodine. Reduction of iodine(III)

Conservation and restoration of leather objects (2,982 words) [view diff] exact match in snippet view article find links to article

that are used in the conservation and restoration of leather. Aluminum alkoxide – 1% in white spirit, used as a chemical restabilizing retanning agent

Ammonolysis (1,017 words) [view diff] exact match in snippet view article find links to article

intermediate. The reformation of the C-O double bond ejects the ester. The alkoxide deprotonates the ammonia forming an alcohol and amide as products. On heating

Non-innocent ligand (1,728 words) [view diff] exact match in snippet view article find links to article

abstracts a hydrogen atom from the alpha-CH functionality of the coordinated alkoxide substrate. The tyrosinyl radical participates in the catalytic cycle: 1e-oxidation

Jonas C. Peters (688 words) [view diff] exact match in snippet view article find links to article

(1996-01-01). "Assembly of Molybdenum/Titanium μ-Oxo Complexes via Radical Alkoxide C−O Cleavage". Journal of the American Chemical Society. 118 (42): 10175–10188

Pechini process (513 words) [view diff] exact match in snippet view article find links to article

and BaTiO3 (Lessing 1989). Unlike the sol–gel process in which the metal alkoxide participates in the gel-forming reactions this process is based on a gelation

Ene reaction (3,349 words) [view diff] exact match in snippet view article find links to article

ene-adduct- Me2AlCl complex can further react to afford methane and aluminum alkoxide, which can prevent proton-catalyzed rearrangements and solvolysis (Figure

Devon W. Meek (402 words) [view diff] exact match in snippet view article find links to article

Devon W. (March 1989). "Synthesis, characterization and reactivity of alkoxide and hydroxide complexes of rhodium(I) and iridium(I)". Organometallics

Richard A. Andersen (chemist) (805 words) [view diff] exact match in snippet view article

Andersen earned his Ph.D. with several fundamental organometallic and alkoxide compounds of beryllium. Andersen then spent a year as postdoctoral researcher

Alcohol fuel (3,336 words) [view diff] exact match in snippet view article find links to article

produce Al2O3, repairing the protective aluminum oxide layer. The aluminum alkoxide does not make a tight oxide layer; water is essential to repair the holes

Polyoxometalate (3,338 words) [view diff] exact match in snippet view article find links to article

recognition. Oxoalkoxometalates are clusters that contain both oxide and alkoxide ligands. Typically they lack terminal oxo ligands. Examples include the

Titanium dioxide (6,569 words) [view diff] exact match in snippet view article find links to article

specialized chemistries. Sol-gel routes involve the hydrolysis of titanium alkoxides, such as titanium ethoxide: Ti(OEt)4 + 2 H2O → TiO2 + 4 EtOH This technology

Common ethanol fuel mixtures (10,699 words) [view diff] exact match in snippet view article find links to article

3,500 ppm water in the E20 experiments by TU Darmstadt the alcoholate/alkoxide corrosion stopped. In the fuel ethanol this resembles 20,000 ppm or 2 volume%

Holton Taxol total synthesis (1,478 words) [view diff] exact match in snippet view article find links to article

group in 46 was deprotected to give alcohol 47. Reaction of the lithium alkoxide of 47 with the Ojima lactam 48 adds the tail in 49. Deprotection of the

Tetrahedral carbonyl addition compound (2,329 words) [view diff] exact match in snippet view article find links to article

5030. doi:10.1021/ja01076a076. Gideon, Fraenkel; Watson Debra (1975). "Alkoxide adduct of an amide. Mean lifetime of an intimate ion pair". J. Am. Chem

Oxoammonium-catalyzed oxidation (1,647 words) [view diff] exact match in snippet view article find links to article

substrate reacts with the N-oxyammonium species. Attack of the substrate alkoxide on either nitrogen or oxygen may occur, although the former is believed

Holton Taxol total synthesis (1,478 words) [view diff] exact match in snippet view article find links to article

group in 46 was deprotected to give alcohol 47. Reaction of the lithium alkoxide of 47 with the Ojima lactam 48 adds the tail in 49. Deprotection of the

Ribonuclease H (5,818 words) [view diff] exact match in snippet view article find links to article

nature and forms an intermediate with protonated phosphate and deprotonated alkoxide leaving group. The leaving group is protonated via the glutamate which

Elias James Corey (5,646 words) [view diff] exact match in snippet view article find links to article

(scheme 19). Proton-transfer provides a dipolar intermediate in which the alkoxide nucleophile attacks the electrophilic carbonyl center, providing a tetrahedral

Chiral auxiliary (3,692 words) [view diff] exact match in snippet view article find links to article

wherein one face of the lithium enolate is blocked by the secondary lithium alkoxide and the solvent molecules associated with that lithium cation. In accordance

Parisa Mehrkhodavandi (1,510 words) [view diff] exact match in snippet view article find links to article

career. In recent works, Mehrkhodavandi writes about the role of the first alkoxide-bridged indium complex and the zinc analogues as important catalysts in

Organolithium reagent (5,971 words) [view diff] exact match in snippet view article find links to article

of aryllithium reagents is often enhanced by the addition of potassium alkoxides. Organolithium reagents can also carry out nucleophilic attacks with epoxides

Pentavalent uranyl complexes (1,066 words) [view diff] exact match in snippet view article find links to article

PMID 11670960. Roussel, P.; Hitchcock, P.B.; Tinker, N.D.; Scott, P. (1997). "Alkoxide and Aryloxide Derivatives of a (Triamidoamine)uranium Complex". Inorg.

Buchwald–Hartwig amination (3,483 words) [view diff] exact match in snippet view article find links to article

hydroxide, carbonate, and phosphate bases in place of the traditional alkoxide and silylamide bases have been developed. The Buchwald group has developed

Enantioselective reduction of ketones (1,406 words) [view diff] exact match in snippet view article find links to article

oxazaborolidine reductions. (1) Lithium aluminium hydride (LAH) modified with chiral alkoxide ligands has been shown to proceed in good yield and high enantioselectivity

Rabeprazole (6,229 words) [view diff] exact match in snippet view article find links to article

of NO2) (2) The newly introduced nitro group is then displaced by the alkoxide from 3-methoxypropanol to yield the corresponding ether (3). Treatment

Polyorthoester (1,749 words) [view diff] exact match in snippet view article find links to article

"Reacting trialkyl orthoformate with boron trifluoride and lactone, then with alkoxide or alkanol and base", published 1991-02-05, assigned to Alza Corp. J.

Reductions with samarium(II) iodide (1,965 words) [view diff] exact match in snippet view article

however, the dimer may undergo either disproportionation to form a samarium alkoxide and carbonyl compound, or protonation to form a carbinol radical ii followed

Titanium adhesive bonding (1,707 words) [view diff] exact match in snippet view article find links to article

cleaner and is often sealed with a primer application like Silane A-187 or alkoxide. Application of the primer can be achieved through manual means, like a

Β-Carbon elimination (1,798 words) [view diff] exact match in snippet view article find links to article

understood than β-alkyl elimination. Examples are reported to occur from metal alkoxide and amido complexes. A theoretical study showed that these reactions are

Discovery and development of beta-blockers (4,063 words) [view diff] exact match in snippet view article find links to article

It consists of phenoxide reacting at the oxirane and resulting in an alkoxide, that displaces the adjacent chloride to form a new epoxide ring. The second

Silsesquioxane (3,746 words) [view diff] exact match in snippet view article find links to article

centers. The fourth group on Si is usually an alkyl, halide, hydride, alkoxide, etc. In the cubic clusters with Oh symmetry the Si-O-Si angles are in

Germanium(II) hydrides (2,198 words) [view diff] exact match in snippet view article

the β-diketiminato germylene hydride to form the corresponding germylene alkoxide in quantitative yield. This reaction proceeds through a nucleophilic hydride

Kedarcidin (2,705 words) [view diff] exact match in snippet view article find links to article

to a cyclic tetrayne was guided by aluminum coordination to a proximal alkoxide, thus generating the desired enediyne core in one step via two successive

Parylene (4,773 words) [view diff] exact match in snippet view article find links to article

and Poly(α,α,α',α'-tetramethyl-p-xylylene)-co-poly(p-xylylene) from Alkoxide Precursors I: Optical Properties and Thermal Stability". Chemical Vapor

Center of Excellence in Nanotechnology (3,245 words) [view diff] exact match in snippet view article find links to article

silica spheres can be obtained from the hydrolysis and condensation of alkoxide silicon by the following methods: Hydrolysis: to form silanol groups Si(OR)

Phosphanide (1,895 words) [view diff] exact match in snippet view article find links to article

PMC 5575506. PMID 28489308. Hendrikus, Hendriksen, Coenradus Johannes (2012). Alkoxide packaged sodium dihydrogenphosphide: synthesis and reactivity (Thesis)

Trifluoromethylation (4,064 words) [view diff] exact match in snippet view article find links to article

0177. Prakash, G. K. Surya; Hu, Jinbo; Olah, George A. (September 2003). "Alkoxide- and Hydroxide-Induced Nucleophilic Trifluoromethylation Using Trifluoromethyl

Metal–organic framework (21,288 words) [view diff] exact match in snippet view article find links to article

Farha OK, Stern CL, Sarjeant AA, Hupp JT (March 2009). "Post-synthesis alkoxide formation within metal-organic framework materials: a strategy for incorporating

Polyfluoroalkoxyaluminates (2,984 words) [view diff] exact match in snippet view article find links to article

Characterisation of Silverpolyfluoroalkoxyaluminates AgAl(ORF)4, Calculation of the Alkoxide Ion Affinity". Chemistry – A European Journal. 7 (2): 490–502. doi:10

Thomas E. Müller (2,254 words) [view diff] exact match in snippet view article find links to article

Thomas E. (July 31, 2015). "Surprisingly facile CO2 insertion into cobalt alkoxide bonds: A theoretical investigation". Beilstein Journal of Organic Chemistry

Molecular layer deposition (8,513 words) [view diff] exact match in snippet view article find links to article

AS, George SM (December 2011). "Molecular layer deposition of aluminum alkoxide polymer films using trimethylaluminum and glycidol". Langmuir. 27 (24):

Nitrate chlorides (3,734 words) [view diff] exact match in snippet view article find links to article

W. (March 1999). "Chloride abstraction activity of Ce(IV) nitrate and alkoxide complexes: Facile formation of [CeCl5(THF)][CeClZ(THF)5] (Z=NO3, Cl)".