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searching for Allylic strain 3 found (12 total)

Radical cyclization (1,902 words) [view diff] exact match in snippet view article find links to article

of transition state models requires consideration of factors such as allylic strain and boat-like transition states (4) Chiral auxiliaries have been used

Petasis reaction (3,232 words) [view diff] exact match in snippet view article find links to article

this case, more reactive) conformation of the ate complex, where 1,3 allylic strain is minimized. With dihydroxyacetone, a somewhat unconventional aldehyde

Discodermolide (3,460 words) [view diff] exact match in snippet view article find links to article

the internal (Z)-alkenes act as conformational locks by minimizing allylic strain and syn-pentane interactions along the backbone. The D-lactone is held