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searching for Bond-dissociation energy 19 found (77 total)

alternate case: bond-dissociation energy

Adenosylcobalamin (341 words) [view diff] no match in snippet view article find links to article

the carbon-cobalt bond. This bond is exceptionally weak, with a bond dissociation energy of 31 kcal/mol, which is further lowered in the chemical environment

Nitroxyl (898 words) [view diff] no match in snippet view article find links to article

form of nitric oxide (NO) and is isoelectronic with dioxygen. The bond dissociation energy of H−NO is 49.5 kcal/mol (207 kJ/mol), which is unusually weak

Hexachlorocyclohexane (437 words) [view diff] no match in snippet view article find links to article

rather than substitution takes place, due to the very high C–H bond dissociation energy (112 kcal/mol) that disfavors abstraction of a hydrogen atom. Addition

Krypton difluoride (1,490 words) [view diff] no match in snippet view article find links to article

difluorine to atomic fluorine requires cleaving a F–F bond with a bond dissociation energy of 36 kcal/mol. Consequently, KrF2 is a good source of the extremely

Diazald (237 words) [view diff] no match in snippet view article find links to article

is thermally sensitive, as a result of its weak N–NO bond whose bond dissociation energy was measured to be 33.4 kcal/mol. External MSDS, Sigma Aldrich

Methane functionalization (2,164 words) [view diff] no match in snippet view article find links to article

Firstly, the C-H bond is extremely inert and non-polar, with a high bond dissociation energy, making methane a relatively unreactive starting material. Secondly

Carbon–hydrogen bond (534 words) [view diff] no match in snippet view article find links to article

Bond Hydrocarbon radical Molar Bond Dissociation Energy (kcal) Molar Bond Dissociation Energy (kJ) CH3−H Methyl 104 440 C2H5−H Ethyl 98 410 (CH3)2HC−H

Organopalladium chemistry (1,043 words) [view diff] no match in snippet view article find links to article

sigma-bonded complexes. The stability of the bonds in terms of bond dissociation energy follows the trend: Pd-Alkynyl > Pd-Vinyl ≈ Pd-Aryl > Pd-Alkyl and

Disulfur decafluoride (654 words) [view diff] no match in snippet view article find links to article

switchgear. S2F10 is also made during the production of SF6. The S-S bond dissociation energy is 305 ± 21 kJ/mol, about 80 kJ/mol stronger than the S-S bond

Carbon group (3,868 words) [view diff] no match in snippet view article find links to article

alkyl derivatives of other groups. In the case of carbon, the high bond dissociation energy of the C–C bond and lack of electronegativity difference between

Allenes (4,081 words) [view diff] no match in snippet view article find links to article

weaker and more acidic compared to typical vinylic C–H bonds: the bond dissociation energy is 87.7 kcal/mol (compared to 111 kcal/mol in ethylene), while

N-Hydroxyphthalimide (1,927 words) [view diff] no match in snippet view article find links to article

acronym being PINO. It is a powerful H-atom abstracting agent. The bond dissociation energy of NHPI (i.e., PINO–H) is 88–90 kcal/mol (370–380 kJ/mol), depending

Neon compounds (4,147 words) [view diff] no match in snippet view article find links to article

adducts), NeBeO is expected to exist, albeit with a very weak bond dissociation energy of 9 kJ/mol. The bond is enhanced by a dipole-induced positive

Stille reaction (5,491 words) [view diff] no match in snippet view article find links to article

in the halogen sequence (its shorter bond length and stronger bond dissociation energy makes it more difficult to break via oxidative addition). Starting

Water (data page) (1,837 words) [view diff] no match in snippet view article

57.98 at 90 °C 55.33 at 100 °C Bond strength 492.215 kJ/mol O–H bond dissociation energy Bond length 95.87 pm (equilibrium) Bond angle 104.48° (equilibrium)

Coinage metal N-heterocyclic carbene complexes (2,695 words) [view diff] no match in snippet view article find links to article

that electrostatic contributions are just one part of the overall bond dissociation energy calculations; while the Ag-NHC bonds have the greatest percentage

Plumbylene (3,070 words) [view diff] no match in snippet view article find links to article

driving force being the relief of steric strain and the low Pb-C bond dissociation energy. Plumbylenes can be used as concurrent σ-donor-σ-acceptor ligands

Phosphasilene (3,350 words) [view diff] no match in snippet view article find links to article

Si-P-H bond angle are calculated to be 2.084 Å and 90.7o. The Si=P bond dissociation energy is 75.0 kcal mol−1 at the B97-D/6-31G(d) level of theory; while

Dispersion stabilized molecules (2,637 words) [view diff] no match in snippet view article find links to article

investigations reveal that the silylated dimer has roughly twice the bond dissociation energy of parent diplumbene Pb2H4 despite the parent diplumbene having