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searching for Claisen condensation 14 found (78 total)

Citrate synthase family (602 words) [view diff] exact match in snippet view article find links to article

bound citryl-coenzyme A intermediate in a 2-step process (aldol-Claisen condensation followed by the hydrolysis of citryl-CoA). Citrate synthase enzymes

Biosynthesis of cocaine (803 words) [view diff] exact match in snippet view article find links to article

through a Claisen condensation. This produces a racemic mixture of the 2-substituted pyrrolidine, with the retention of the thioester from the Claisen condensation

Hentriacontanonaene (547 words) [view diff] exact match in snippet view article find links to article

two acyl-CoA or acyl-ACP are condensed using a non-decarboxylative Claisen condensation to yield a β-keto-thioester. Hydrolysis from the enzyme is followed

Paralytic shellfish poisoning (1,417 words) [view diff] exact match in snippet view article find links to article

chemical reactions (among which is a rare chemical reaction known as a Claisen condensation), going through four intermediates before resulting in saxitoxin

Acetyl-CoA C-acetyltransferase (288 words) [view diff] exact match in snippet view article find links to article

Asn316 and His348 for stabilizing the enolate intermediate of the Claisen condensation". Biochemistry. 48 (46): 11011–25. doi:10.1021/bi901069h. PMID 19842716

Malate synthase (2,446 words) [view diff] exact match in snippet view article find links to article

Knowles JR (August 1988). "Malate synthase: proof of a stepwise Claisen condensation using the double-isotope fractionation test". Biochemistry. 27 (16):

Cyclopentyl methyl ether (1,058 words) [view diff] exact match in snippet view article find links to article

Reaction etc. Reactions using Organometallic reagents or basic agents: Claisen condensation, formation of enolates or Grignard reaction. Reduction and oxidation

Hyperforin (1,728 words) [view diff] exact match in snippet view article find links to article

Two acylphloroglucinoal cores PICP and PIBP formed are formed by claisen condensation but will differ in substrate and enzyme specificities. PIVP will

Ketoacyl synthase (2,238 words) [view diff] exact match in snippet view article find links to article

enzyme is used to construct fatty acyl chains through a three step Claisen condensation reaction. The reaction will start with a trans thioesterfication

Pyrrole (3,142 words) [view diff] exact match in snippet view article find links to article

domain, followed by transfer to malonyl-ACP via decarboxylative Claisen condensation. This fragment is then able to react with the masked carbanion formed

Amphotericin B (4,068 words) [view diff] exact match in snippet view article find links to article

acetyl transferase (AT). The ACP-bound elongation group reacts in a Claisen condensation with the KS-bound polyketide chain. Ketoreductase (KR), dehydratase

Cocaine (17,673 words) [view diff] exact match in snippet view article find links to article

through a Claisen condensation. This produces a racemic mixture of the 2-substituted pyrrolidine, with the retention of the thioester from the Claisen condensation

4-Ipomeanol (3,270 words) [view diff] exact match in snippet view article find links to article

heating with a copper powder yielded ethyl 3-furoate (III). The Claisen condensation is used to form ethyl 3-furoylacetate (IV). By reacting with propylene

Discodermolide (3,460 words) [view diff] exact match in snippet view article find links to article

methodology for the production of the polypropionate backbone. They used a Claisen condensation reaction to construct the C(13)–C(14) trisubstituted Z-olefin. The