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searching for Metal–halogen exchange 10 found (17 total)

Phenylsodium (980 words) [view diff] no match in snippet view article find links to article

Phenylsodium C6H5Na is an organosodium compound. Solid phenylsodium was first isolated by Nef in 1903. Although the behavior of phenylsodium and phenyl

Organosodium chemistry (1,261 words) [view diff] no match in snippet view article find links to article

Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds

1,3-Bis(diphenylphosphino)propane (350 words) [view diff] exact match in snippet view article

synthesised via a much more controllable (and cheaper) route, via metal-halogen exchange and then metathesis: Br(CH2)3Br + 2 tBuLi → Li(CH2)3Li + 2 tBuBr

Corey–House synthesis (1,517 words) [view diff] exact match in snippet view article find links to article

nucleophiles, such a process rarely works well in practice due to metal–halogen exchange and/or the formation of large amounts of reduction or elimination

Doering–LaFlamme allene synthesis (395 words) [view diff] exact match in snippet view article find links to article

magnesium, or with an organolithium reagent. Either approach results in metal-halogen exchange to convert the gem-dihalogenated carbon to a 1-metallo-1-halocyclopropane

Grignard reagent (2,664 words) [view diff] case mismatch in snippet view article find links to article

"Preparation of t-Butyl-3-Bromo-5-Formylbenzoate Through Selective Metal-Halogen Exchange Reactions". Organic Syntheses. 89: 460. doi:10.15227/orgsyn.089

Phenyllithium (656 words) [view diff] exact match in snippet view article find links to article

2Li → Ph-Li + LiX Phenyllithium can also be synthesized with a metal-halogen exchange reaction: n-BuLi + X-Ph → n-BuX + Ph-Li The predominant method of

Thiazole (1,150 words) [view diff] exact match in snippet view article find links to article

replacing the proton. 2-Lithiothiazoles are also generated by metal-halogen exchange from 2-bromothiazole. Electrophilic aromatic substitution at C5

Group 2 organometallic chemistry (2,000 words) [view diff] case mismatch in snippet view article find links to article

"Preparation of t-Butyl-3-Bromo-5-Formylbenzoate Through Selective Metal-Halogen Exchange Reactions". Organic Syntheses. 89: 460. doi:10.15227/orgsyn.089

Alkali metal (23,537 words) [view diff] exact match in snippet view article find links to article

may be used to synthesise other organometallic compounds through metal-halogen exchange.: 106 Unlike the organolithium compounds, the organometallic compounds