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Longer titles found: F-block metallocene (view), Post-metallocene catalyst (view), Ansa-metallocene (view), Bent metallocene (view)

searching for Metallocene 41 found (133 total)

alternate case: metallocene

Medium-density polyethylene (170 words) [view diff] exact match in snippet view article find links to article

be produced by chromium/silica catalysts, Ziegler-Natta catalysts or metallocene catalysts. MDPE has good shock and drop resistance properties. It also
Methylaluminoxane (567 words) [view diff] exact match in snippet view article find links to article
as zirconacene dichloride. In the mid-1970s Kaminsky discovered that metallocene dichlorides can be activated by MAO (see Kaminsky catalyst). The effect
2,2'-Bis(2-indenyl) biphenyl (245 words) [view diff] exact match in snippet view article
[C6H4C9H7]2. The compound is the precursor, upon deprotonation, to ansa-metallocene complexes within the area of transition metal indenyl complexes. Metals
Titanocene Y (1,111 words) [view diff] exact match in snippet view article find links to article
039. Köpf H, Köpf-Maier P (1979). "Titanocene dichloride--the first metallocene with cancerostatic activity". Angew. Chem. Int. Ed. Engl. 18 (6): 477–478
Dehydrogenative coupling of silanes (1,021 words) [view diff] no match in snippet view article find links to article
The dehydrogenative coupling of silanes is a reaction type for the formation of Si-Si bonds. Although never commercialized[citation needed], the reaction
Tuck-in complex (425 words) [view diff] exact match in snippet view article find links to article
; Evans, W. J. (2010). "Reactivity of Tuck-in and Tuck-over Uranium Metallocene Complexes". Organometallics. 29: 4159–4170. doi:10.1021/om1007538. Sun
Cyclopentadienyl anion (232 words) [view diff] exact match in snippet view article find links to article
Metallocene structure where "M" is a metal
Single-molecule magnet (3,168 words) [view diff] exact match in snippet view article find links to article
Mansikkamäki, Akseli; Layfield, Richard A. (2017-09-11). "A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit". Angewandte Chemie
Ferrocenium tetrafluoroborate (360 words) [view diff] exact match in snippet view article find links to article
are known. According to X-ray crystallography, the structures of the metallocene component of FcBF4 and the parent ferrocene are very similar. The Fe-C
Organocobalt chemistry (1,095 words) [view diff] exact match in snippet view article find links to article
cobaltocene, a rare example of low-spin Co(II) complex. This 19-electron metallocene is used as a reducing agent and as a source of CpCo. Other sandwich compounds
Polyolefin (1,162 words) [view diff] exact match in snippet view article find links to article
"A WAXD/SAXS/DSC study on the melting behavior of Ziegler-Natta and metallocene catalyzed isotactic polypropylene". Journal of Polymer Science Part B:
Chain-growth polymerization (2,707 words) [view diff] exact match in snippet view article find links to article
polymer effectively. In addition, the racemic mixture of the chiral metallocene can be separated into its enantiomers. The oligomerization reaction produces
Titanocene bis(trimethylsilyl)acetylene (1,850 words) [view diff] exact match in snippet view article
Ti-C(sp2) σ-bonds. Researchers have calculated the bonding nature of various metallocene acetylene complexes. Cp2Ti(η2-Me3SiC2SiMe3) was modeled using a B3LYP
Dalton Transactions (677 words) [view diff] exact match in snippet view article find links to article
1039/B305705B. S2CID 96914248. M Bochmann (1996). "Cationic Group 4 metallocene complexes and their role in polymerisation catalysis: the chemistry of
Decamethylferrocene (603 words) [view diff] exact match in snippet view article find links to article
decamethylmanganocene and decamethylferrocene. Static Jahn-Teller distortion in a metallocene". J. Am. Chem. Soc. 101 (4): 892–897. doi:10.1021/ja00498a017. Su, Bin;
Tacticity (1,734 words) [view diff] exact match in snippet view article find links to article
if that looser usage is explained. Syndiotactic polystyrene, made by metallocene catalysis polymerization, is crystalline with a melting point of 161 °C
Terbium (3,799 words) [view diff] exact match in snippet view article find links to article
Long, J. R. (2019-08-21). "Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)". Journal of the American
Paper bag (4,327 words) [view diff] exact match in snippet view article find links to article
Fapet Oy. pp. 121–122. ISBN 978-952-5216-18-9. Fiscus, D M (2004). "Metallocene LLDPE Films for Heavy-Duty Sack Applications". Journal of Plastic Film
Copolymer (4,267 words) [view diff] exact match in snippet view article find links to article
Gerhard (1998). "Ethene−Norbornene Copolymerization with Homogeneous Metallocene and Half-Sandwich Catalysts: Kinetics and Relationships between Catalyst
Chemistry (9,163 words) [view diff] exact match in snippet view article find links to article
Retrieved 1 April 2024. Kaminsky, Walter (1 January 1998). "Highly active metallocene catalysts for olefin polymerization". Journal of the Chemical Society
Russell P. Hughes (1,036 words) [view diff] exact match in snippet view article find links to article
770 °C) to extrude CO from an oxacyclohexadienyl complex led to the first metallocene containing a perfluorinated cyclopentadienyl ring, η5-C5F5. Direct comparison
John Meurig Thomas (5,252 words) [view diff] exact match in snippet view article find links to article
1990. Solid acid catalysts Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica Design, synthesis and in situ characterisation
Stephen Conway (cricketer) (165 words) [view diff] exact match in snippet view article
Conway, Stephen L. J. (2000). "Structure reactivity relationships in metallocene chemistry: the ansa-effect". {{cite journal}}: Cite journal requires
Bismuth organometallic chemistry (1,573 words) [view diff] exact match in snippet view article find links to article
center and simultaneously π* back-bonding to the bismuth cluster from the metallocene complex. In 2009, Pearl et al. described the synthesis and isomerization
Anthony J. Dias (200 words) [view diff] exact match in snippet view article find links to article
responsibilities. His most cited scientific work concerned the development of metallocene catalysts on a nonreacting polystrene support to replace reactive silica
1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene (320 words) [view diff] exact match in snippet view article
compound with the salts of main-group and transition metals. The resulting metallocenes, in contrast to the unsubstituted Pentaphenylcyclopentadienyl complexes
Carol J. Burns (616 words) [view diff] exact match in snippet view article find links to article
et al. (1 September 2009). "Trends in covalency for d- and f-element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy
Rufina Alamo (574 words) [view diff] exact match in snippet view article find links to article
Mandelkern, L. (July 2003), "Formation of the α and γ polymorphs in random metallocene-propylene copolymers: Effect of concentration and type of comonomer"
Klaus-Dieter Hungenberg (736 words) [view diff] exact match in snippet view article find links to article
Progress in Gas Phase Polymerization of Propylene with Supported TiCl4 and Metallocene Catalysts. Vol. 89. pp. 373–380. doi:10.1016/s0167-2991(08)63051-7. ISBN 9780444986566
Polystyrene (8,596 words) [view diff] exact match in snippet view article find links to article
produced under the trade name XAREC by Idemitsu corporation, who use a metallocene catalyst for the polymerisation reaction. Polystyrene is relatively chemically
Uranium(III) bromide (206 words) [view diff] exact match in snippet view article
Kiplinger, Jaqueline (2016-01-06). "Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent
National Medal of Technology and Innovation (722 words) [view diff] exact match in snippet view article find links to article
John A. Ewen "For his basic discoveries and inventions in the field of metallocene catalysis which have revolutionized the production of polyethylene and
Phosphinidene (2,005 words) [view diff] exact match in snippet view article find links to article
first synthesis of a stable terminal phosphinidene complex: lithium metallocene hydrides [Cp2MHLi]4 of Mo and W were reacted with aryl-dichlorophosphines
Photo-oxidation of polymers (4,972 words) [view diff] exact match in snippet view article find links to article
Anwar (December 2010). "Effect of selected residual Ziegler–Natta and metallocene catalysts on the UV-induced degradation of unstabilized ethylene homopolymer
IUPAC polymer nomenclature (1,716 words) [view diff] exact match in snippet view article find links to article
inorganic and inorganic-organic polymers, for example those containing metallocene derivatives, are at present best named using organic nomenclature, e
Tris(trimethylsilyl)amine (1,628 words) [view diff] exact match in snippet view article
smaller than, for example, the modern polymerization catalysts of the metallocene type or enzymes. J. Goubeau, J. Jiminéz-Barberá (1960), "Tris-(trimethylsilyl)-amin"
Willard Gibbs Award (5,878 words) [view diff] exact match in snippet view article find links to article
oxide chemical vapor deposition, high temperature superconductors, and metallocene anti-tumor agents." Ralph Hirschmann 2002 "For the first synthesis of
William J. Evans (chemist) (1,010 words) [view diff] exact match in snippet view article
(O2CC=C=O)2-. Desolvation of (C5Me5)2Sm(THF)2 formed the first bent metallocene with no other ligands, (C5Me5)2Sm. Decamethylsamarocene, as it was called
Anthony J. Arduengo (4,758 words) [view diff] exact match in snippet view article find links to article
Marshall; M. Tamm (1999). "Adducts of Carbenes with Group II and XII Metallocenes". Organometallics. 17 (15): 3375–3382. doi:10.1021/om980438w. A. J. Arduengo;
Alexander Nesmeyanov (4,211 words) [view diff] exact match in snippet view article find links to article
the electronic effects of the substituents are transmitted through the metallocene core by an inductive mechanism, and therefore have a lesser effect than
Sodium dicarbollylcobaltate(III) (1,025 words) [view diff] exact match in snippet view article
(February 1968). ".pi.-Dicarbollyl derivatives of the transition metals. Metallocene analogs". Journal of the American Chemical Society. 90 (4): 879–896.