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Longer titles found: (Trimethylsilyl)methyllithium (view)

searching for Methyllithium 13 found (59 total)

Tris(trimethylsilyl)methane (189 words) [view diff] exact match in snippet view article

tris(trimethylsilyl)methane with methyl lithium gives tris(trimethylsilyl)methyllithium, called trisyllithium. Trisyllithium is useful in Petersen olefination

Chloro(triphenylphosphine)gold(I) (581 words) [view diff] exact match in snippet view article

transmetalation with a Grignard reagent. Further treatment of Ph3PAuMe with methyllithium displaces the phosphine ligand and generates lithium di- and tetramethylaurate

Rimantadine (1,532 words) [view diff] exact match in snippet view article find links to article

reduced with sodium borohydride to create racemic hydroxy acid. Excess methyllithium is then added to create methyl ketones which when reduced with lithium

Corey–Seebach reaction (770 words) [view diff] exact match in snippet view article find links to article

Dieter (1 December 1966). "Phenylthiomethyllithium and Bis(phenylthio)methyllithium". The Journal of Organic Chemistry. 31 (12): 4097–4099. doi:10.1021/jo01350a052

Organotitanium chemistry (1,866 words) [view diff] exact match in snippet view article find links to article

dimethyl titanocene (1990) is prepared from titanocene dichloride and methyllithium in diethyl ether. Compared to Tebbe's reagent it is easier to prepare

Trimethylsilyldiazomethane (650 words) [view diff] exact match in snippet view article find links to article

; Shioiri, Takayuki; Aoyama, Toyohiko (2011). "Diazo(trimethylsilyl)methyllithium". E-EROS Encyclopedia of Reagents for Organic Synthesis. pp. 1–7. doi:10

Carbanion (3,430 words) [view diff] exact match in snippet view article find links to article

product with retention of configuration: Of recent date are chiral methyllithium compounds: The phosphate 1 contains a chiral group with a hydrogen and

Payne rearrangement (1,773 words) [view diff] exact match in snippet view article find links to article

0° was added dropwise over about 5 minutes 2.76 mL of a solution of methyllithium in ethyl ether (1.4 M, 3.86 mmol). The colorless solution was stirred

Lutetium compounds (1,801 words) [view diff] exact match in snippet view article find links to article

be obtained by reacting lutetium(III) chloride and (trimethylsilyl)methyllithium in a solvent containing tetrahydrofuran (THF). Adding ammonia water

Boron (12,785 words) [view diff] exact match in snippet view article find links to article

common e.g. lithium fluoride, lithium hydroxide, lithium amide, and methyllithium, but lithium boryllides are extraordinarily rare. Strong bases do not

1,3-Dipolar cycloaddition (6,426 words) [view diff] exact match in snippet view article find links to article

"Untersuchungen an Diazomethanen, VI. Mitteil.: Umsetzung von Diazoäthan mit Methyllithium". Chemische Berichte. 89 (4): 1065–1071. doi:10.1002/cber.19560890436

Murahashi coupling (655 words) [view diff] exact match in snippet view article find links to article

Palladium-Catalyzed C(Sp3)–C(Sp2) Cross-Coupling of (Trimethylsilyl)Methyllithium with (Hetero)Aryl Halides. Org. Lett. 2015, 17 (9), 2262–2265. https://doi

Nikolay Zefirov (1,590 words) [view diff] exact match in snippet view article find links to article

"Unusual rearrangement of triangulane gem-dibromides in the presence of methyllithium". Tetrahedron. 48 (45): 9977–9984. doi:10.1016/S0040-4020(01)92287-2