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searching for Thiolactone 5 found (11 total)

alternate case: thiolactone

Fukuyama coupling (901 words) [view diff] exact match in snippet view article find links to article

to the thiolactone intermediate 1. Shimizu and Seki realized the efficient synthesis of (+)-biotin via the Fukuyama coupling of the thiolactone 1 and an
Bleomycin hydrolase (1,028 words) [view diff] exact match in snippet view article find links to article
biological function is hydrolysis of the reactive electrophile homocysteine thiolactone. Another of its activities is metabolic inactivation of the glycopeptide
Accessory gene regulator (1,004 words) [view diff] exact match in snippet view article find links to article
transcriptional quorum-sensing (QS) system activated by an autoinducing, thiolactone-containing cyclic peptide (AIP). Agr occurs in 4 allelic subtypes that
Homocysteine (2,001 words) [view diff] exact match in snippet view article find links to article
for methionine synthase. Homocysteine can cyclize to give homocysteine thiolactone, a five-membered heterocycle. Because of this "self-looping" reaction
Organozinc chemistry (3,394 words) [view diff] exact match in snippet view article find links to article
(+)-biotin. In this case, the Fukuyama coupling takes place with the thiolactone: The Barbier reaction involves nucleophilic addition of a carbanion equivalent