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searching for Asymmetric induction 27 found (53 total)

Ene reaction (3,349 words) [view diff] exact match in snippet view article find links to article

carbonyl groups. The catalysts were found to afford high levels of asymmetric induction in several processes, including the ene reaction of ethyl glyoxylate

1,3-Dipolar cycloaddition (6,426 words) [view diff] exact match in snippet view article find links to article

in particular Rh2[(S)-DOSP]4 and Rh2[(S)-BPTV]4 can induce modest asymmetric induction and was used to synthesize the antifungal agent pseudolaric acid

Asymmetric nucleophilic epoxidation (1,634 words) [view diff] exact match in snippet view article find links to article

reaction have taken advantage of a number of strategies for achieving asymmetric induction. The highest yielding and most enantioselective methods include:

Α-Ketol rearrangement (1,281 words) [view diff] exact match in snippet view article find links to article

also be influenced through conformational control and often exhibit asymmetric induction. Disadvantages: Because the reaction is reversible and thermodynamically

Enantioselective reduction of ketones (1,406 words) [view diff] exact match in snippet view article find links to article

transfer of an H2 molecule from the reductant to the substrate. Asymmetric induction in transition metal catalyzed reactions is achieved through the use

Chugaev elimination (291 words) [view diff] case mismatch in snippet view article find links to article

"Studies in Stereochemistry. X. The Rule of "Steric Control of Asymmetric Induction" in the Syntheses of Acyclic Systems". Journal of the American Chemical

Reformatsky reaction (1,269 words) [view diff] exact match in snippet view article find links to article

Etter, Jeffrey B. (1987). "Lanthanides in organic synthesis. 8. 1.3-Asymmetric induction in intramolecular Reformatskii-type reactions promoted by samarium

Jonathan Clayden (352 words) [view diff] case mismatch in snippet view article find links to article

(3 January 2014). "Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction" (PDF). Angewandte Chemie International Edition. 53 (1): 151–155

Allylic strain (2,466 words) [view diff] exact match in snippet view article find links to article

deprotonation to occur. In an intramolecular Diels-Alder reaction, asymmetric induction can be induced through allylic 1,3 strain on the diene or the dienophile

Chiraphos (179 words) [view diff] exact match in snippet view article find links to article

demonstration of how the conformation of the chelate ring can affect asymmetric induction by a metal catalyst. Prior to this work, in most chiral phosphines

Megaphone (molecule) (383 words) [view diff] exact match in snippet view article

of (-)-megaphone by a highly controlled consecutive 1,4- and 1,3-asymmetric induction". Tetrahedron Letters. 26 (7): 903–906. doi:10.1016/S0040-4039(00)61960-3

Tsuji–Trost reaction (2,771 words) [view diff] exact match in snippet view article find links to article

Asymmetric induction in allylic alkylations." J. Am. Chem. Soc. 1973, 95, 8200–8201. doi:10.1021/ja00805a056. Trost, B. M.; Strege, P. E. "Asymmetric

Sue Gibson (chemist) (722 words) [view diff] exact match in snippet view article

and peptide synthesis, medicinal chemistry, macrocycle synthesis, asymmetric induction, dendrimer construction, linker technology and multi-component catalysis

Sharpless asymmetric dihydroxylation (2,175 words) [view diff] exact match in snippet view article find links to article

ISBN 3-527-30642-0 Hentges, Steven G.; Sharpless, K. Barry (June 1980). "Asymmetric induction in the reaction of osmium tetroxide with olefins". J. Am. Chem. Soc

Abramov reaction (1,098 words) [view diff] exact match in snippet view article find links to article

context, and bases such as sodium amide have been used. However, asymmetric induction and selective direct addition (for conjugated carbonyl compounds)

Carbene (2,400 words) [view diff] exact match in snippet view article find links to article

insertions are seen. Both inter- and intra-molecular insertions admit asymmetric induction from a chiral metal catalyst. Carbenes can form adducts with nucleophiles

Josiphos ligands (1,265 words) [view diff] exact match in snippet view article find links to article

ISSN 1615-4150. Whitesell, James K. (1989-11-01). "C2 symmetry and asymmetric induction". Chemical Reviews. 89 (7): 1581–1590. doi:10.1021/cr00097a012. ISSN 0009-2665

Diisopinocampheylborane (871 words) [view diff] case mismatch in snippet view article find links to article

Asymmetric Synthesis via Hydroboration with Essentially Complete Asymmetric Induction". Israel Journal of Chemistry. 15 (1–2): 12–16. doi:10.1002/ijch

Claisen rearrangement (2,490 words) [view diff] case mismatch in snippet view article find links to article

(2): 115–116. doi:10.1039/p19960000115. Nubbemeyer, U. (1995). "1,2-Asymmetric Induction in the Zwitterionic Claisen Rearrangement of Allylamines". J. Org

Erythromycin (3,748 words) [view diff] case mismatch in snippet view article find links to article

Erythromycin. 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction". Journal of the American Chemical Society. 103 (11): 3210–3213.

Proline organocatalysis (1,841 words) [view diff] exact match in snippet view article find links to article

erythromcin. 1. Synthesis of an erythronolide a secoacid derivative via asymmetric induction". Journal of the American Chemical Society. 103 (11): 3210. doi:10

Yoon Nung-min (521 words) [view diff] case mismatch in snippet view article find links to article

Asymmetric Synthesis via Hydroboration with Essentially Complete Asymmetric Induction (H. C. Brown and N. M. Yoon), Israel J. Chem Vol.15 p. 12 (1976~1977)

Organolithium reagent (5,971 words) [view diff] exact match in snippet view article find links to article

obtained through asymmetric metalation of prochiral substrates. Asymmetric induction requires the presence of a chiral ligand such as (-)-sparteine. The

Donna Nelson (4,475 words) [view diff] case mismatch in snippet view article find links to article

Comprehensive Analysis of Relative Reactivities, Stereochemistry and Asymmetric Induction, and Their Comparisons with Sulfenylation".Beilstein J. Org. Chem

Asymmetric hydrogenation (6,355 words) [view diff] exact match in snippet view article find links to article

1021/ja211658t. PMID 22448656. Whitesell, J. K. (1989). "C2 symmetry and asymmetric induction". Chemical Reviews. 89 (7): 1581–1590. doi:10.1021/cr00097a012. Knowles

Borylation (3,976 words) [view diff] exact match in snippet view article find links to article

(S)-(+)-benzyl-alpha-d alcohol with an essentially quantitative asymmetric induction. In the same year, M. M. Midland discovered B-3-alpha-pinanyl-9-BBN

Dialkylbiaryl phosphine ligands (3,942 words) [view diff] case mismatch in snippet view article find links to article

via Pd-Catalyzed Alkene Carboamination Reactions. Control of 1,3-Asymmetric Induction by Manipulating Mechanistic Pathways". Organic Letters. 16 (12):